| Literature DB >> 16330831 |
Sung-Nak Choi1, Sang-Yub Kim, Hae-Wook Ryu, Yong-Min Lee.
Abstract
In the title compound, [HgCl2(C15H26N2)], the chiral alkaloid (6R,7S,8S,14S)-(-)-L-sparteine acts as a bidentate ligand, with two Cl- ligands occupying the remaining coordination sites, producing a distorted tetrahedron. The N-Hg-N plane is twisted by 81.1 (2) degrees from the Cl-Hg-Cl plane. The mid-point of the N...N line does not lie exactly on the Cl-Hg-Cl plane but is tilted towards one of the N atoms by 0.346 angstroms. Similarly, the mid-point of the Cl...Cl line is tilted toward one of the Cl atoms by 0.163 angstroms. The packing structure shows that the complex is stabilized by two interatomic Cl...H contacts involving both Cl atoms and the methylene or methine H atoms of the (-)-sparteine ligand.Entities:
Year: 2005 PMID: 16330831 DOI: 10.1107/S0108270105033858
Source DB: PubMed Journal: Acta Crystallogr C ISSN: 0108-2701 Impact factor: 1.172