Literature DB >> 16330831

Dichloro[(6R,7S,8S,14S)-(-)-sparteine-kappa2N,N']mercury(II).

Sung-Nak Choi1, Sang-Yub Kim, Hae-Wook Ryu, Yong-Min Lee.   

Abstract

In the title compound, [HgCl2(C15H26N2)], the chiral alkaloid (6R,7S,8S,14S)-(-)-L-sparteine acts as a bidentate ligand, with two Cl- ligands occupying the remaining coordination sites, producing a distorted tetrahedron. The N-Hg-N plane is twisted by 81.1 (2) degrees from the Cl-Hg-Cl plane. The mid-point of the N...N line does not lie exactly on the Cl-Hg-Cl plane but is tilted towards one of the N atoms by 0.346 angstroms. Similarly, the mid-point of the Cl...Cl line is tilted toward one of the Cl atoms by 0.163 angstroms. The packing structure shows that the complex is stabilized by two interatomic Cl...H contacts involving both Cl atoms and the methylene or methine H atoms of the (-)-sparteine ligand.

Entities:  

Year:  2005        PMID: 16330831     DOI: 10.1107/S0108270105033858

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri-methyl-ethane-1,2-di-amine-κ(2) N,N')di-chloridomercury(II).

Authors:  Sudesh T Manjare; Harkesh B Singh; Ray J Butcher
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-08-06
  1 in total

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