Literature DB >> 16323855

Synthesis and structural characterization of carborane-containing neutral, self-assembled Pt-metallacycles.

Neeladri Das1, Peter J Stang, Atta M Arif, Charles F Campana.   

Abstract

[structure: see text] We have combined carborane chemistry with the newly developed directional bonding strategy to synthesize neutral macrocycles. The m- and p-carborane dicarboxylates were utilized as the donor linkers in conjunction with 1,8-bis[trans-Pt(PEt3)2NO3]anthracene 3, 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene 5, and cis-Pt(PEt3)2(NO3)2 unit 6. Three new platinum-based macrocycles, 4, 7, and 8, were thus synthesized. 31P{1H} NMR as well as the X-ray characterization of Pt-metallacycles reveal the formation of single highly symmetrical neutral species.

Entities:  

Year:  2005        PMID： 16323855     DOI： 10.1021/jo0517085

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  7 in total

Review 1.  Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.

Authors:  Rajesh Chakrabarty; Partha Sarathi Mukherjee; Peter J Stang
Journal:  Chem Rev       Date:  2011-08-24       Impact factor: 60.622

2.  Construction of endo-functionalized two dimensional metallacycles via coordination-driven self-assembly.

Authors:  Liang Zhao; Koushik Ghosh; Yao-Rong Zheng; Peter J Stang
Journal:  J Org Chem       Date:  2009-11-20       Impact factor: 4.354

3.  Facile self-assembly of neutral dendritic metallocycles via oxygen-to-platinum coordination.

Authors:  Hai-Bo Yang; Brian H Northrop; Yao-Rong Zheng; Koushik Ghosh; Peter J Stang
Journal:  J Org Chem       Date:  2009-09-18       Impact factor: 4.354

Review 4.  Coordination-driven self-assembly of functionalized supramolecular metallacycles.

Authors:  Brian H Northrop; Hai-Bo Yang; Peter J Stang
Journal:  Chem Commun (Camb)       Date:  2008-09-01       Impact factor: 6.222

Review 5.  Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors:  Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal:  Chem Rev       Date:  2012-11-02       Impact factor: 60.622

6.  From solvolysis to self-assembly.

Authors:  Peter J Stang
Journal:  J Org Chem       Date:  2009-01-02       Impact factor: 4.354

7.  Anthracene-induced formation of highly twisted metallacycle and its crystal structure and tunable assembly behaviors.

Authors:  Chongyi Chen; Yan Sun; Yue Zhao; Ryan T VanderLinden; Wei Tuo; Fengmin Zhang; Shuwei Zhang; Hajar Sepehrpour; Chaoguo Yan; Jin Wang; Dan Li; Peter J Stang
Journal:  Proc Natl Acad Sci U S A       Date:  2021-07-06       Impact factor: 11.205
  7 in total

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