Literature DB >> 16321000

Chiral phosphite-oxazolines: a new class of ligands for asymmetric Heck reactions.

Yvette Mata1, Montserrat Diéguez, Oscar Pàmies, Carmen Claver.   

Abstract

[chemical reaction: see text]. A series of phosphite-oxazoline ligands, derived from readily available D-glucosamine, have been used for the first time in the palladium-catalyzed Heck reaction of several substrates with high regio- and enantioselectivities (ee's up to 99%) and improved activities in standard conditions.

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Year:  2005        PMID: 16321000     DOI: 10.1021/ol052176h

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Bis(oxazolines) based on glycopyranosides - steric, configurational and conformational influences on stereoselectivity.

Authors:  Tobias Minuth; Mike M K Boysen
Journal:  Beilstein J Org Chem       Date:  2010-03-04       Impact factor: 2.883

2.  Rational design of cyclopropane-based chiral PHOX ligands for intermolecular asymmetric Heck reaction.

Authors:  Marina Rubina; William M Sherrill; Alexey Yu Barkov; Michael Rubin
Journal:  Beilstein J Org Chem       Date:  2014-07-07       Impact factor: 2.883

Review 3.  Carbohydrates as enantioinduction components in stereoselective catalysis.

Authors:  Alexander S Henderson; John F Bower; M Carmen Galan
Journal:  Org Biomol Chem       Date:  2016-04-26       Impact factor: 3.876

  3 in total

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