Literature DB >> 16317461

Selective site controlled nucleophilic attacks in 5-membered ring phosphate esters: unusual C-O vs. common P-O bond cleavage.

Nissan Ashkenazi1, Sanjio S Zade, Yoffi Segall, Yishai Karton, Michael Bendikov.   

Abstract

Clean endocyclic C-O bond cleavage has been achieved in the reactions of 5-membered phosphate triesters with various nucleophiles.

Entities:  

Year:  2005        PMID: 16317461     DOI: 10.1039/b512117e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Synthesis of γ-hydroxypropyl P-chirogenic (±)-phosphorus oxide derivatives by regioselective ring-opening of oxaphospholane 2-oxide precursors.

Authors:  Iris Binyamin; Shoval Meidan-Shani; Nissan Ashkenazi
Journal:  Beilstein J Org Chem       Date:  2015-07-30       Impact factor: 2.883

  1 in total

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