Polarization of water near dipolar surfaces: a simple model for anomalous dielectric behavior.

A model for the electrostatic interactions in water in the vicinity of a surface is suggested, which accounts, within the Poisson-Boltzmann mean field approach, for the screening of the charges and for the coupling interactions between neighboring dipoles. When the water molecules near a solid surface are assumed to be organized in icelike layers, the polarization is not a continuous function but exists only at the discrete positions of the water molecules. The particular positions of the water molecules in the icelike structure govern the manner in which the average water dipoles align with each other. On the basis of this model, one could explain the nonmonotonic behavior of the polarization and the electrical potential as well as the anomalous dielectric response of water (the nonproportionality of the polarization and the macroscopic electric field), which were obtained recently via molecular dynamics simulations.