Literature DB >> 16307141

Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides.

Marie E Krafft1, Kimberly A Seibert, Thomas F N Haxell, Chitaru Hirosawa.   

Abstract

sp3 Hybridized electrophiles, never before used in the organomediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.

Entities:  

Year:  2005        PMID： 16307141     DOI： 10.1039/b512665g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Cu-catalyzed cross-dehydrogenative coupling: a versatile strategy for C-C bond formations via the oxidative activation of sp(3) C-H bonds.

Authors:  Zhiping Li; D Scott Bohle; Chao-Jun Li
Journal:  Proc Natl Acad Sci U S A       Date:  2006-06-05       Impact factor: 11.205

2.  Umpolung of Michael acceptors catalyzed by N-heterocyclic carbenes.

Authors:  Christian Fischer; Sean W Smith; David A Powell; Gregory C Fu
Journal:  J Am Chem Soc       Date:  2006-02-08       Impact factor: 15.419

3.  Novel Organic-Inorganic Perovskite Compounds Having Phosphonium Groups.

Authors:  Shunsuke Shimizu; Masahiro Yoshizawa-Fujita; Yuko Takeoka; Masahiro Rikukawa
Journal:  ACS Omega       Date:  2019-08-06

4.  Crystal structure and Hirshfeld surface analysis of 7,7-dimethyl-2-phenyl-3,3a,4,6,7,8,9,9a-octa-hydro-1H-benzo[f]iso-indole-1,5(2H)-dione.

Authors:  Dong Cheng; Xinlei Gao; Jiating Huang; Xiang-Zhen Meng
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-03-10

5.  Me2(CH2[double bond, length as m-dash]CH)SiCN: a bifunctional ethylene equivalent for Diels-Alder reaction based controllable tandem synthesis.

Authors:  Wen-Biao Wu; Bo-Shuai Mu; Jin-Sheng Yu; Jian Zhou
Journal:  Chem Sci       Date:  2022-02-24       Impact factor: 9.825

6.  Efficient 1,4-addition of alpha-substituted fluoro(phenylsulfonyl)methane derivatives to alpha,beta-unsaturated compounds.

Authors:  G K Surya Prakash; Xiaoming Zhao; Sujith Chacko; Fang Wang; Habiba Vaghoo; George A Olah
Journal:  Beilstein J Org Chem       Date:  2008-05-21       Impact factor: 2.883
  6 in total

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