Concentrations of ambient air particulates (TSP, PM2.5 and PM2.5-10) and ionic species at offshore areas near Taiwan Strait.

The concentrations of total suspended particulate (TSP), fine particles PM(2.5) (with aerodynamic diameter <2.5 microm), coarse particles PM(2.5-10) (with aerodynamic diameter 2.5-10 microm,), and water-soluble inorganic ions were studied at two offshore sampling sites, Taichung Harbor (TH) and Wuci Traffic (WT), near Taiwan Strait in central Taiwan during March 2004 to January 2005. Statistical analyses were also carried out to estimate the possible sources of particulate pollution. Experimental results showed that the average mass concentrations of TSP, PM(2.5) and PM(2.5-10) at TH and WT sampling sites were 154.54 +/- 31.45 and 113.59 +/- 31.94 microg m(-3), 54.03 +/- 16.92 and 42.76 +/- 12.52 microg m(-3), and 30.31+/- 9.79 and 24.16 +/- 7.27 microg m(-3), respectively. The dominant inorganic ions at two sampling sites were SO(4)(2-), NO(3)(-), and NH(4)(+) for TSP and PM(2.5), but that were Ca(2+), Cl(-), and Na(+) for PM(2.5-10). The concentrations of most particulates and inorganic ions were higher in winter at both two sampling sites, and were higher at TH than WT sampling site in each season. From statistical analysis, air-slake of crust surface, sea-salt aerosols, agriculture activities, coal combustion, and mobile vehicles were the possible emission sources of particulate pollution at TH and WT sampling sites.