Literature DB >> 16292908

Why is hydrofluoric acid a weak acid?

Patrick Ayotte1, Martin Hébert, Patrick Marchand.   

Abstract

The infrared vibrational spectra of amorphous solid water thin films doped with HF at 40 K reveal a strong continuous absorbance in the 1000-3275 cm(-1) range. This so-called Zundel continuum is the spectroscopic hallmark for aqueous protons. The extensive ionic dissociation of HF at such low temperature suggests that the reaction enthalpy remains negative down to 40 K. These observations support the interpretation that dilute HF aqueous solutions behave as weak acids largely due to the large positive reaction entropy resulting from the structure making character of the hydrated fluoride ion.

Entities:  

Year:  2005        PMID: 16292908     DOI: 10.1063/1.2090259

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  3 in total

1.  Eukaryotic resistance to fluoride toxicity mediated by a widespread family of fluoride export proteins.

Authors:  Sanshu Li; Kathryn D Smith; Jared H Davis; Patricia B Gordon; Ronald R Breaker; Scott A Strobel
Journal:  Proc Natl Acad Sci U S A       Date:  2013-10-30       Impact factor: 11.205

2.  Effects of 2% sodium fluoride solution on the prevention of streptococcal adhesion to titanium and zirconia surfaces.

Authors:  Yukari Oda; Tadashi Miura; Tomoki Hirano; Yoshitaka Furuya; Taichi Ito; Masao Yoshinari; Yasutomo Yajima
Journal:  Sci Rep       Date:  2021-02-24       Impact factor: 4.379

3.  Reaction Mechanisms during Atomic Layer Deposition of AlF3 Using Al(CH3)3 and SF6 Plasma.

Authors:  Martijn F J Vos; Harm C M Knoops; Wilhelmus M M Kessels; Adriaan J M Mackus
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2021-02-10       Impact factor: 4.126

  3 in total

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