| Literature DB >> 16292855 |
Margarita Ortiz-Marciales1, Luis D Rivera, Melvin De Jesús, Sandraliz Espinosa, Josúe A Benjamin, Orlando E Casanova, Irving G Figueroa, Sheila Rodríguez, Wilbert Correa.
Abstract
[reaction: see text] Aromatic O-triisopropylsilyl ketoximes were efficiently rearranged to cyclic and acyclic aniline derivatives on reduction with BF3-ethearate/borane. The bulk of the substituents on the silicon atom, the size of the aliphatic ring, and the presence of alkoxy substituents on the aryl group all play an important role in the aniline.Entities:
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Year: 2005 PMID: 16292855 DOI: 10.1021/jo0516178
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354