| Literature DB >> 16290386 |
Lunxiang Yin1, Yanqin Wang, Guangsheng Pang, Yuri Koltypin, Aharon Gedanken.
Abstract
Cerium oxide (CeO(2)) nanoparticles were prepared sonochemically, by using cerium nitrate and azodicarbonamide as starting materials, and ethylenediamine or tetraalkylammonium hydroxide as additives. The additives have a strong effect on the particle size and particle size distribution. CeO(2) nanoparticles with small particle size and narrow particle size distribution are obtained with the addition of additives; while highly agglomerated CeO(2) nanoparticles are obtained in the absence of additives. Monodispersed CeO(2) nanoparticles with a mean particle size of ca. 3.3 nm are obtained when tetramethylammonium hydroxide (TMAOH) is used as the additive and the molar ratio of cerium nitrate/azodicarbonamine/TMAOH is 1/1/1. Blue shifts of the absorption peak and the absorption edges of the products are observed in the UV-Vis absorption spectra as a result of the quantum size effect. The samples have been characterized using powder XRD, TEM, DLS, and absorption spectra.Entities:
Year: 2002 PMID: 16290386 DOI: 10.1006/jcis.2001.8047
Source DB: PubMed Journal: J Colloid Interface Sci ISSN: 0021-9797 Impact factor: 8.128