Speciation of heavy metals during co-composting of sewage sludge with lime.

During composting the humification of organic matter will have a significant effect on the physicochemical form of existence of heavy metals. Therefore the present study was conducted to investigate the effect of co-composting sewage sludge with lime on heavy metal speciation and the changes in DTPA extractable metals. Metal speciation was conducted to evaluate the redistribution of Cu, Mn, Ni, Pb and Zn in sewage sludge composted with lime. Sewage sludge was mixed with sawdust in 2:1 (w/w fresh weight) and then composted with lime at 0%, 0.63%, 1% or 1.63% (dry weight) for 100 days. The lime addition did not cause any changes in the different forms of Cu and Mn, but the composting process caused transformations of residual form of Cu and Mn into oxidizable and reducible form, respectively. For Ni, the reducible form was mainly transformed into residual form and lime addition decreased this transformation. Major transformation of different forms of Pb was not found, however the residual form of Pb increased with lime addition. The predominant residual form of Zn was mainly transformed into oxidizable form and the lime addition reduced this transformation. Addition of lime to sewage sludge during composting resulted in lower DTPA extractable metal contents. Therefore, lime is a suitable material to co-compost with sewage sludge to reduce the availability of heavy metals.