Literature DB >> 16268563

General synthesis of thiophene and selenophene-based heteroacenes.

Toshihiro Okamoto1, Kenichi Kudoh, Atsushi Wakamiya, Shigehiro Yamaguchi.   

Abstract

[reaction: see text] A new intramolecular triple cyclization of bis(o-haloaryl)diacetylenes, via dilithiation followed by reaction with chalcogen elements, produces pi-conjugated compounds containing heterole-1,2-dichalcogenin-heterole fused tricyclic skeletons. The subsequent dechalcogenation with copper metal affords a series of thiophene- and selenophene-based heteroacenes.

Entities:  

Year:  2005        PMID: 16268563     DOI: 10.1021/ol0523650

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Thiophene/selenophene-based S-shaped double helicenes: regioselective synthesis and structures.

Authors:  Mengjie Wang; Lanping Dang; Wan Xu; Zhiying Ma; Liuliu Shao; Guangxia Wang; Chunli Li; Hua Wang
Journal:  Beilstein J Org Chem       Date:  2022-07-08       Impact factor: 2.544

2.  Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely π-extended thienoacenes.

Authors:  Feng Su; Shuqi Chen; Xiaogang Mo; Kongchuan Wu; Jiajun Wu; Weidong Lin; Zhiwei Lin; Jianbin Lin; Hui-Jun Zhang; Ting-Bin Wen
Journal:  Chem Sci       Date:  2019-12-20       Impact factor: 9.825

  2 in total

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