Literature DB >> 16261232

pi-Face donor properties of N-heterocyclic carbenes.

Marcus Süssner1, Herbert Plenio.   

Abstract

The donor properties of aryl substituted N-heterocyclic carbenes are characterized by lone pair donation from the carbene carbon and, as is shown here, by donation of electron density of the aromatic pi-face of the NHC aryl groups towards the metal.

Entities:  

Year:  2005        PMID： 16261232     DOI： 10.1039/b512008j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  A comparison between oxazoline-imidazolinylidene, -imidazolylidine, -benzimidazolylidene hydrogenation catalysts.

Authors:  Sakunchai Khumsubdee; Yubo Fan; Kevin Burgess
Journal:  J Org Chem       Date:  2013-09-19       Impact factor: 4.354

2.  Improved ruthenium catalysts for Z-selective olefin metathesis.

Authors:  Benjamin K Keitz; Koji Endo; Paresma R Patel; Myles B Herbert; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2011-12-09       Impact factor: 15.419

3.  The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition.

Authors:  Giovanni Occhipinti; Daniel L Nascimento; Marco Foscato; Deryn E Fogg; Vidar R Jensen
Journal:  Chem Sci       Date:  2022-03-22       Impact factor: 9.969
  3 in total

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