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Literature DB >> 16258611

Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II).

Cynthia Brewer¹, Greg Brewer, Ray J Butcher, Everett E Carpenter, Luciann Cuenca, Ann M Schmiedekamp, Carol Viragh.

Abstract

The iron(II) and manganese(II) complexes of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, approximately 2.44 è, metal to apical nitrogen bond.

Year: 2005 PMID： 16258611 DOI： 10.1039/b511566c

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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1 in total

1. Synthesis and characterization of manganese(II) and iron(III) d5 tripodal imidazole complexes. Effect of oxidation state, protonation state and ligand conformation on coordination number and spin state.

Authors: Cynthia Brewer; Greg Brewer; Ray J Butcher; Everett E Carpenter; Luciann Cuenca; Bruce C Noll; W Robert Scheidt; Carol Viragh; Peter Y Zavalij; Daniel Zielaski
Journal: Dalton Trans Date: 2005-12-23 Impact factor: 4.390

1 in total