Literature DB >> 16244729

Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes.

Antonia Black1, John M Brown, Christophe Pichon.   

Abstract

The hydroboration of stilbenes and related disubstituted alkenes catalysed by QUINAP complexes may proceed with high enantio- and regioselectivity; rhodium and iridium catalysts give the same product regioisomer but opposite enantiomers.

Entities:  

Year:  2005        PMID: 16244729     DOI: 10.1039/b508292g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Remarkable levels of enantioswitching in catalytic asymmetric hydroboration.

Authors:  Sean M Smith; James M Takacs
Journal:  Org Lett       Date:  2010-10-15       Impact factor: 6.005

  1 in total

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