Melting of copper and nickel at high pressure: the role of d electrons.

Melting curves of Cu and Ni were measured in the laser-heated diamond cell to 97 GPa (3800 K) and 60 GPa (2970 K), respectively. The temperatures of Cu are in good agreement with recent theoretical calculations. The Cu melting slope (dT/dP) is about 2.5 times steeper than for Ni. The present results confirm the key role d-shell electrons play in determining the temperature dependence of high pressure melting curves in transition metals that have filled or partially filled d electron bands.