| Literature DB >> 16241117 |
Kelly Servaes1, Christoph Hennig, Rik Van Deun, Christiane Görller-Walrand.
Abstract
The complex formation of uranyl UO(2)(2+) with chloride ions in acetonitrile was studied by UV-vis and U L(III) EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO(2)Cl(4)](2-) species in solution with D(4)(h)() symmetry. The distances in the U(VI) coordination sphere are U-O(ax) = 1.77 +/- 0.01 Angstroms and U-Cl = 2.68 +/- 0.01 Angstroms.Entities:
Year: 2005 PMID： 16241117 DOI： 10.1021/ic051098r
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165