Literature DB >> 16238351

Efficient two-step synthesis of 9-aryl-6-hydroxy-3H-xanthen-3-one fluorophores.

James P Bacci1, Aaron M Kearney, David L Van Vranken.   

Abstract

[reaction: see text] A two-step method for the synthesis of 9-aryl-6-hydroxy-3H-xanthen-3-one fluorophores involving condensation of aryl aldehydes and fluororesorcinol is shown to proceed through a triarylmethane intermediate. The condensation is complicated by retro-Friedel-Crafts reactions which can be minimized by controlling the amount of acid. The xanthenone ring system is prepared by a final oxidative cyclization with DDQ.

Entities:  

Mesh：

Substances：

Year:  2005        PMID： 16238351     DOI： 10.1021/jo051243i

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  An organic white light-emitting fluorophore.

Authors:  Youjun Yang; Mark Lowry; Corin M Schowalter; Sayo O Fakayode; Jorge O Escobedo; Xiangyang Xu; Huating Zhang; Timothy J Jensen; Frank R Fronczek; Isiah M Warner; Robert M Strongin
Journal:  J Am Chem Soc       Date:  2006-11-01       Impact factor: 15.419

2.  An efficient and green one-pot synthesis of tetrahydrobenzo[a]xanthenes, 1,8-dioxo-octahydroxanthenes and dibenzo[a,j]xanthenes by Fe3O4@Agar-Ag as nanocatalyst.

Authors:  Kimia Hoseinzade; Seyed Ali Mousavi-Mashhadi; Ali Shiri
Journal:  Mol Divers       Date:  2022-01-29       Impact factor: 3.364

3.  One-Pot Synthesis of New Symmetric and Asymmetric Xanthene Dyes.

Authors:  Scott A Hilderbrand; Ralph Weissleder
Journal:  Tetrahedron Lett       Date:  2007-06-18       Impact factor: 2.415

4.  Design, synthesis and antiviral potential of 14-aryl/heteroaryl-14H-dibenzo[a,j]xanthenes using an efficient polymer-supported catalyst.

Authors:  Kalla Reddi Mohan Naidu; Balam Satheesh Krishna; Mungara Anil Kumar; Palanisamy Arulselvan; Shaik Ibrahim Khalivulla; Ola Lasekan
Journal:  Molecules       Date:  2012-06-18       Impact factor: 4.411
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.