Literature DB >> 16238350

Palladium-catalyzed conversion of benzylic and allylic halides into alpha-aryl and beta,gamma-unsaturated tertiary amides by the use of a carbamoylsilane.

Robert F Cunico1, Rajesh K Pandey.   

Abstract

[reaction: see text] Treatment of allylic and benzylic halides with N,N-dimethylcarbamoyl(trimethyl)silane in the presence of tetrakis(triphenylphosphine)palladium(0) affords tertiary amides, which arise from the replacement of the halogen by the N,N-dimethylcarbamoyl group.

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Year:  2005        PMID： 16238350     DOI： 10.1021/jo0512406

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane.

Authors:  Yves Canac; Greg E Aniol; Salvador Conejero; Bruno Donnadieu; Guy Bertrand
Journal:  Eur J Inorg Chem       Date:  2006-12-01       Impact factor: 2.524

Review 2.  Heterogeneous Phase Microwave-Assisted Reactions under CO₂ or CO Pressure.

Authors:  Emanuela Calcio Gaudino; Laura Rinaldi; Laura Rotolo; Diego Carnaroglio; Camillo Pirola; Giancarlo Cravotto
Journal:  Molecules       Date:  2016-02-24       Impact factor: 4.411

3.  Preparation of Functionalized Amides Using Dicarbamoylzincs.

Authors:  Dimitrije Djukanovic; Maximilian A Ganiek; Kohei Nishi; Konstantin Karaghiosoff; Kazushi Mashima; Paul Knochel
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-13       Impact factor: 16.823
  3 in total

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