Literature DB >> 16235964

Pd-catalyzed silicon hydride reductions of aromatic and aliphatic nitro groups.

Ronald J Rahaim1, Robert E Maleczka.   

Abstract

[reaction: see text] Room-temperature reduction of aromatic nitro groups to amines can be accomplished in high yield, with wide functional group tolerance and short reaction times (30 min) using a combination of palladium(II) acetate, aqueous potassium fluoride, and polymethylhydrosiloxane (PMHS). Replacing PMHS/KF with triethylsilane allows aliphatic nitro groups to be reduced to their hydroxylamines.

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Year:  2005        PMID： 16235964     DOI： 10.1021/ol052120n

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Competition between [2 + 1]- and [4 + 1]-cycloaddition mechanisms in reactions of conjugated nitroalkenes with dichlorocarbene in the light of a DFT computational study.

Authors:  Radwan A Alnajjar; Radomir Jasiński
Journal:  J Mol Model       Date:  2019-05-11       Impact factor: 1.810

2.  CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe3E2(CO)9, E = S, Se, Te).

Authors:  Charu Sharma; Avinash Kumar Srivastava; Aditi Soni; Sangeeta Kumari; Raj Kumar Joshi
Journal:  RSC Adv       Date:  2020-09-01       Impact factor: 4.036

3.  Development of highly selective casein kinase 1δ/1ε (CK1δ/ε) inhibitors with potent antiproliferative properties.

Authors:  Mathieu Bibian; Ronald J Rahaim; Jun Yong Choi; Yoshihiko Noguchi; Stephan Schürer; Weimin Chen; Shima Nakanishi; Konstantin Licht; Laura H Rosenberg; Lin Li; Yangbo Feng; Michael D Cameron; Derek R Duckett; John L Cleveland; William R Roush
Journal:  Bioorg Med Chem Lett       Date:  2013-05-31       Impact factor: 2.823

4.  Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

Authors:  Wei Feng; Tingting Huang; Liqian Gao; Xianfeng Yang; Wenbin Deng; Rui Zhou; Hongjun Liu
Journal:  RSC Adv       Date:  2018-02-07       Impact factor: 3.361

5.  Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles.

Authors:  Mangal S Yadav; Anoop S Singh; Anand K Agrahari; Nidhi Mishra; Vinod K Tiwari
Journal:  ACS Omega       Date:  2019-04-11
  5 in total

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