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Literature DB >> 16231387

Synthesis of borirenes by photochemical borylene transfer from [(OC)5M==BN(SiMe3)2] (M=Cr, Mo) to alkynes.

Holger Braunschweig¹, Thomas Herbst, Daniela Rais, Fabian Seeler.

Abstract

Entities: Chemical

Year: 2005 PMID： 16231387 DOI： 10.1002/anie.200502524

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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3 in total

1. Unsupported boron-carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation.

Authors: Holger Braunschweig; Peter Brenner; Rian D Dewhurst; Ivo Krummenacher; Bernd Pfaffinger; Alfredo Vargas
Journal: Nat Commun Date: 2012-05-29 Impact factor: 14.919

2. Controlled homocatenation of boron on a transition metal.

Authors: Holger Braunschweig; Qing Ye; Alfredo Vargas; Rian D Dewhurst; Krzysztof Radacki; Alexander Damme
Journal: Nat Chem Date: 2012-06-17 Impact factor: 24.427

3. Synthesis of unsymmetrical B₂E₂ and B₂E₃ heterocycles by borylene insertion into boradichalcogeniranes.

Authors: Siyuan Liu; Marc-André Légaré; Alexander Hofmann; Anna Rempel; Stephan Hagspiel; Holger Braunschweig
Journal: Chem Sci Date: 2019-03-19 Impact factor: 9.825

3 in total

Synthesis of borirenes by photochemical borylene transfer from [(OC)5M==BN(SiMe3)2] (M=Cr, Mo) to alkynes.

1. Unsupported boron-carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation.

2. Controlled homocatenation of boron on a transition metal.

3. Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes.

3. Synthesis of unsymmetrical B₂E₂ and B₂E₃ heterocycles by borylene insertion into boradichalcogeniranes.