Literature DB >> 16218613

A mild radical procedure for the reduction of B-alkylcatecholboranes to alkanes.

Davide Pozzi1, Eoin M Scanlan, Philippe Renaud.   

Abstract

A mild radical-mediated reduction of organoboranes is reported. The reducing agent is methanol complexed by the Lewis acidic B-methoxycatecholborane.

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Year:  2005        PMID: 16218613     DOI: 10.1021/ja055691j

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  11 in total

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4.  An intramolecular coupling approach to alkyl bioisosteres for the synthesis of multisubstituted bicycloalkyl boronates.

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6.  Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds.

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Journal:  J Am Chem Soc       Date:  2016-07-22       Impact factor: 15.419

7.  Boron tribromide as a reagent for anti-Markovnikov addition of HBr to cyclopropanes.

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8.  Mechanistic aspects of the isomerization of Z-vinylic tellurides double bonds in the synthesis of potassium Z-vinyltrifluoroborate salts.

Authors:  Hélio A Stefani; Rafael C Guadagnin; Artur F Keppler; Giancarlo V Botteselle; João V Comasseto; Carlos A Suganuma
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9.  Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air.

Authors:  Florent Allais; Jean Boivin; Van Tai Nguyen
Journal:  Beilstein J Org Chem       Date:  2007-12-12       Impact factor: 2.883

10.  Part 1. Reduction of S-alkyl-thionocarbonates and related compounds in the presence of trialkylboranes/air.

Authors:  Jean Boivin; Van Tai Nguyen
Journal:  Beilstein J Org Chem       Date:  2007-12-12       Impact factor: 2.883

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