Literature DB >> 16209625

Direct atom-efficient esterification between carboxylic acids and alcohols catalyzed by amphoteric, water-tolerant TiO(acac)2.

Chien-Tien Chen1, Yogesh S Munot.   

Abstract

A diverse array of oxometallic species were examined as catalysts for a test direct condensation of benzoic acid and 2-phenylethanol in 1:1 stoichiometry. Besides group IVB MOCl2-xH2O and TiOX2-xH2O, group VB VOCl2-xTHF and group IVB TiO(acac)2 were found to be the most efficient and water-tolerant catalysts for the test reaction. The new neutral catalytic protocol with the optimal TiO(acac)2 tolerates many stereo/electronic structural variations in both (di)acid (1 degree -3 degrees alkyl and aryl) and (di)alcohol (1 degree, 2 degrees alkyl, and aryl) components with high chemoselectivity.

Entities:  

Year:  2005        PMID： 16209625     DOI： 10.1021/jo051337s

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  5 in total

1.  Performance-advantaged ether diesel bioblendstock production by a priori design.

Authors:  Nabila A Huq; Xiangchen Huo; Glenn R Hafenstine; Stephen M Tifft; Jim Stunkel; Earl D Christensen; Gina M Fioroni; Lisa Fouts; Robert L McCormick; Patrick A Cherry; Charles S McEnally; Lisa D Pfefferle; Matthew R Wiatrowski; P Thathiana Benavides; Mary J Biddy; Raynella M Connatser; Michael D Kass; Teresa L Alleman; Peter C St John; Seonah Kim; Derek R Vardon
Journal:  Proc Natl Acad Sci U S A       Date:  2019-12-16       Impact factor: 11.205

2.  Chiral N-salicylidene vanadyl carboxylate-catalyzed enantioselective aerobic oxidation of alpha-hydroxy esters and amides.

Authors:  Shiue-Shien Weng; Mei-Wen Shen; Jun-Qi Kao; Yogesh S Munot; Chien-Tien Chen
Journal:  Proc Natl Acad Sci U S A       Date:  2006-02-24       Impact factor: 11.205

3.  In-Water and Neat Batch and Continuous-Flow Direct Esterification and Transesterification by a Porous Polymeric Acid Catalyst.

Authors:  Heeyoel Baek; Maki Minakawa; Yoichi M A Yamada; Jin Wook Han; Yasuhiro Uozumi
Journal:  Sci Rep       Date:  2016-05-18       Impact factor: 4.379

4.  Synthesis of Thiol Derivatives of Biological Active Compounds for Nanotechnology Application.

Authors:  Katarzyna Sidoryk; Olga Michalak; Marek Kubiszewski; Andrzej Leś; Marcin Cybulski; Elżbieta U Stolarczyk; Jan Doubsky
Journal:  Molecules       Date:  2020-07-30       Impact factor: 4.411

5.  Bioactive Diterpenes, Norditerpenes, and Sesquiterpenes from a Formosan Soft Coral Cespitularia sp.

Authors:  You-Cheng Lin; Chi-Chien Lin; Yi-Chia Chu; Chung-Wei Fu; Jyh-Horng Sheu
Journal:  Pharmaceuticals (Basel)       Date:  2021-12-01
  5 in total

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