| Literature DB >> 16190702 |
Rowshan Ara Begum1, Nripen Chanda, T V V Ramakrishna, Paul R Sharp.
Abstract
Treatment of the four-membered platinacycle L2Pt(1,8-naphthalendiyl) (1) or the five-membered platinacycle L2Pt(1,12-triphenylendiyl) with excess PhCCPh at 120-150 degrees C gives the coupling products 1,2-diphenylacenaphthalene or 4,5-diphenylbenzo[e]pyrene and the alkyne complex L2Pt(eta2-PhCCPh). Both reactions show an accelerating rate, which has been traced to catalysis of the reaction by colloidal platinum formed by the reaction of O2 with L2Pt(eta2-PhCCPh).Entities:
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Year: 2005 PMID： 16190702 DOI： 10.1021/ja054863+
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419