Literature DB >> 16180847

Highly stable gold(III) complex with a hydantoin ligand in alkaline media.

Kenichi Oyaizu1, Yutaka Ohtani, Asako Shiozawa, Kenji Sugawara, Takashi Saito, Makoto Yuasa.   

Abstract

A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)4]-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

Entities:  

Year:  2005        PMID： 16180847     DOI： 10.1021/ic050515x

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  In-situ microscale spectrophotometric determination of phenytoin by using branched gold nanoparticles.

Authors:  Maryam Khoubnasabjafari; Azam Samadi; Abolghasem Jouyban
Journal:  Mikrochim Acta       Date:  2019-06-11       Impact factor: 5.833

2.  Electroless deposition of Ni-P/Au coating on Cu substrate with improved corrosion resistance from Au(iii)-DMH based cyanide-free plating bath using hypophosphite as a reducing agent.

Authors:  Bo Wu; Baizhao Tan; Guizhen Tan; Ming Zeng; Jinyi Luo; Guanghui Hu; Jiye Luo; Zhifeng Hao; Shaomei Lai; Binyun Liu
Journal:  RSC Adv       Date:  2021-12-08       Impact factor: 4.036

3.  Theoretical and experimental studies of the influence of gold ions and DMH on cyanide-free gold electrodeposition.

Authors:  Xuefeng Ren; Maozhong An
Journal:  RSC Adv       Date:  2018-01-12       Impact factor: 3.361
  3 in total

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