Literature DB >> 16175292

Heck-type 5-endo-trig cyclization promoted by vinylic fluorines: synthesis of 5-fluoro-3H-pyrroles.

Kotaro Sakoda1, Jun Mihara, Junji Ichikawa.   

Abstract

A 5-endo-trig alkene insertion proceeds under palladium catalysis via aminopalladium species starting from 3,3-difluoroallyl ketone O-pentafluorobenzoyloximes, providing a facile access to 5-fluoro-3H-pyrroles.

Entities:  

Year:  2005        PMID： 16175292     DOI： 10.1039/b510039a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

Review 1.  Cross-Coupling of Heteroatomic Electrophiles.

Authors:  Katerina M Korch; Donald A Watson
Journal:  Chem Rev       Date:  2019-06-11       Impact factor: 60.622

2.  Rhodium-catalysed C(sp(2))-C(sp(2)) bond formation via C-H/C-F activation.

Authors:  Panpan Tian; Chao Feng; Teck-Peng Loh
Journal:  Nat Commun       Date:  2015-06-17       Impact factor: 14.919

3.  Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles.

Authors:  Nicholas J Race; Ian R Hazelden; Adele Faulkner; John F Bower
Journal:  Chem Sci       Date:  2017-06-20       Impact factor: 9.825

4.  DFT Studies on Ni-Mediated C-F Cleavage for the Synthesis of Cyclopentadiene Derivatives.

Authors:  Wen-Jie Chen; Ruo-Nan Xu; Weimin Lin; Xuejiao Sun; Bin Wang; Qi-Hui Wu; Xin Huang
Journal:  Front Chem       Date:  2018-08-13       Impact factor: 5.221

5.  Palladium-catalyzed heck coupling reaction of aryl bromides in aqueous media using tetrahydropyrimidinium salts as carbene ligands.

Authors:  Sedat Yaşar; Emine Ozge Ozcan; Nevin Gürbüz; Bekir Cetinkaya; Ismail Ozdemir
Journal:  Molecules       Date:  2010-01-28       Impact factor: 4.411

6.  Effect of CO Molecule Orientation on the Reduction of Cu-Based Nanoparticles.

Authors:  Sergey Y Sarvadii; Andrey K Gatin; Vasiliy A Kharitonov; Nadezhda V Dokhlikova; Sergey A Ozerin; Maxim V Grishin; Boris R Shub
Journal:  Nanomaterials (Basel)       Date:  2021-01-22       Impact factor: 5.076

7.  Palladium-catalysed difluoroolefination of benzyl tosylates toward the synthesis of gem-difluoro-2-trifluromethyl styrene derivatives.

Authors:  Jie Xu; Jiangjun Liu; Gang Chen; Baojian Xiong; Xuemei Zhang; Zhong Lian
Journal:  RSC Adv       Date:  2022-04-28       Impact factor: 4.036
  7 in total

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