| Literature DB >> 16161617 |
Abstract
We calculate the mean end-to-end distance R of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius D. A self-consistent perturbation theory is used to calculate R as a function of D for impenetrable hard walls and soft walls. In both cases, R obeys the predicted scaling behavior in the limit of large and small D. The crossover from the three-dimensional behavior (D --> infinity) to the fully stretched one-dimensional case (D --> 0) is nonmonotonic. The minimum value of R is found at D approximately 0.46R(F), where R(F) is the Flory radius of R at D --> infinity. The results for soft walls map onto the hard wall case with a larger cylinder radius.Entities:
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Year: 2005 PMID: 16161617 DOI: 10.1063/1.1903923
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488