Literature DB >> 16149801

Stereoselective syntheses of (+/-)-komaroviquinone and (+/-)-faveline methyl ether through intramolecular Heck reaction.

Sujaya Sengupta1, Michael G B Drew, Ranjan Mukhopadhyay, Basudeb Achari, Asish Kr Banerjee.   

Abstract

[reaction: see text] An efficient, flexible, and stereoselective convergent route for constructing the trans-10-hydroxy-1,1-dimethyloctahydrodibenzo[a,d]cyclohepten-7-ones (5a-c) was achieved via intramolecular Heck reaction. This strategy has been successfully implemented for the syntheses of (+/-)-komaroviquinone (3) through (+/-)-coulterone dimethyl ether (5c) and (+/-)-faveline methyl ether (1a).

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Year:  2005        PMID: 16149801     DOI: 10.1021/jo051082i

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  A Rh(II)-catalyzed cycloaddition approach towards the synthesis of komaroviquinone.

Authors:  Albert Padwa; Majid J Chughtai; Jutatip Boonsombat; Paitoon Rashatasakhon
Journal:  Tetrahedron       Date:  2008-05-19       Impact factor: 2.457

2.  Total Synthesis of the Schisandraceae Nortriterpenoid Rubriflordilactone A.

Authors:  Guilhem Chaubet; Shermin S Goh; Mujahid Mohammad; Birgit Gockel; Marie-Caroline A Cordonnier; Hannah Baars; Andrew W Phillips; Edward A Anderson
Journal:  Chemistry       Date:  2017-09-08       Impact factor: 5.236

  2 in total

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