Literature DB >> 16146397

Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates.

Wenzhong Gao1, Xumu Zhang, Malati Raghunath.   

Abstract

[reaction: see text] A novel Cu(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with acrylates has been developed. Up to 98/2 exo/endo selectivity and up to 98% enantiomeric excess have been achieved.

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Year:  2005        PMID: 16146397     DOI: 10.1021/ol0516925

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Catalytic Asymmetric Synthesis of Highly Substituted Pyrrolizidines.

Authors:  Andrew D Lim; Julian A Codelli; Sarah E Reisman
Journal:  Chem Sci       Date:  2012-11-13       Impact factor: 9.825

2.  Development of chiral metal amides as highly reactive catalysts for asymmetric [3 + 2] cycloadditions.

Authors:  Yasuhiro Yamashita; Susumu Yoshimoto; Mark J Dutton; Shū Kobayashi
Journal:  Beilstein J Org Chem       Date:  2016-07-13       Impact factor: 2.883

3.  Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions.

Authors:  Irina A Utepova; Polina O Serebrennikova; Marina S Streltsova; Alexandra A Musikhina; Tatiana G Fedorchenko; Oleg N Chupakhin; Andrey P Antonchick
Journal:  Molecules       Date:  2018-05-30       Impact factor: 4.411

4.  Catalytic asymmetric synthesis of enantioenriched α-deuterated pyrrolidine derivatives.

Authors:  Xin Chang; Xiang Cheng; Chun-Jiang Wang
Journal:  Chem Sci       Date:  2022-03-17       Impact factor: 9.825

  4 in total

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