Literature DB >> 16144401

Synthesis, characterization, and energetic properties of diazido heteroaromatic high-nitrogen C-N compound.

My Hang V Huynh1, Michael A Hiskey, David E Chavez, Darren L Naud, Richard D Gilardi.   

Abstract

The synthesis, characterization, and energetic properties of diazido heteroaromatic high-nitrogen C-N compound, 3,6-diazido-1,2,4,5-tetrazine (DiAT), are reported. Its normalized heat of formation (NDeltaHf), experimentally determined using an additive method, is shown to be the highest positive NDeltaHf compared to all other organic molecules. The unexpected azido-tetrazolo tautomerizations and irreversible tetrazolo transformation of DiAT are remarkable compared to all other polyazido heteroaromatic high-nitrogen C-N compounds, for example, 2,4,6-triazido-1,3,5-triazine; 4,4',6,6'-tetra(azido)hydrazo-1,3,5-triazine; 4,4',6,6'-tetra(azido)azo-1,3,5-triazine; and 2,5,8-tri(azido)-1,3,4,6,7,9,9b-heptaazaphenalene (heptazine).

Entities:  

Mesh：

Substances：

Year:  2005        PMID： 16144401     DOI： 10.1021/ja0509735

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

1.  Design and selection of nitrogen-rich bridged di-1,3,5-triazine derivatives with high energy and reduced sensitivity.

Authors:  Yong Pan; Weihua Zhu; Heming Xiao
Journal:  J Mol Model       Date:  2012-01-03       Impact factor: 1.810

2.  Divergent Synthesis of Monosubstituted and Unsymmetrical 3,6-Disubstituted Tetrazines from Carboxylic Ester Precursors.

Authors:  Yixin Xie; Yinzhi Fang; Zhen Huang; Amanda M Tallon; Christopher W Am Ende; Joseph M Fox
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-07       Impact factor: 15.336

3.  Characterization of nitrogen-bridged 1,2,4,5-tetrazine-, furazan-, and 1H-tetrazole-based polyheterocyclic compounds: heats of formation, thermal stability, and detonation properties.

Authors:  Tao Wei; Jianzhang Wu; Weihua Zhu; Chenchen Zhang; Heming Xiao
Journal:  J Mol Model       Date:  2012-01-27       Impact factor: 1.810

4.  Computational investigations into the substituent effects of -N₃, -NF₂, -NO₂, and -NH₂ on the structure, sensitivity and detonation properties of N, N'-azobis(1,2,4-triazole).

Authors:  Junqing Yang; Hua Yan; Guixiang Wang; Xueli Zhang; Tianyi Wang; Xuedong Gong
Journal:  J Mol Model       Date:  2014-03-22       Impact factor: 1.810

5.  QSPR modeling of detonation parameters and sensitivity of some energetic materials: DFT vs. PM3 calculations.

Authors:  Jianying Zhang; Gangling Chen; Xuedong Gong
Journal:  J Mol Model       Date:  2017-05-22       Impact factor: 1.810

6.  Synthesis and Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl halides.

Authors:  Gary A Molander; Inji Shin
Journal:  Org Lett       Date:  2011-07-06       Impact factor: 6.005

7.  Dinitroamino benzene derivatives: a class new potential high energy density compounds.

Authors:  Qiang Cao
Journal:  J Mol Model       Date:  2013-01-29       Impact factor: 1.810

8.  Green primary explosives: 5-nitrotetrazolato-N2-ferrate hierarchies.

Authors:  My Hang V Huynh; Michael D Coburn; Thomas J Meyer; Modi Wetzler
Journal:  Proc Natl Acad Sci U S A       Date:  2006-06-27       Impact factor: 11.205

9.  Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl mesylates.

Authors:  Gary A Molander; Inji Shin
Journal:  Org Lett       Date:  2012-05-31       Impact factor: 6.005

10.  Theoretical studies on the heats of formation, densities, and detonation properties of substituted s-tetrazine compounds.

Authors:  Yang Zhou; XinPing Long; YuanJie Shu
Journal:  J Mol Model       Date:  2009-11-13       Impact factor: 1.810
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.