Literature DB >> 16144392

Structural determination of metallofullerene Sc3C82 revisited: a surprising finding.

Yuko Iiduka1, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, Akihiro Sakuraba, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Tatsuhisa Kato, Michael T H Liu, Naomi Mizorogi, Kaoru Kobayashi, Shigeru Nagase.   

Abstract

We report here the structural determination of the Sc3C82 molecule by 13C NMR spectroscopy and X-ray single-crystal structure analysis. From the present study, it is obvious that the structure of Sc3C82 is not Sc3@C82 but Sc3C2@C80.

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Year:  2005        PMID： 16144392     DOI： 10.1021/ja054209u

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  Theoretical study on aluminum carbide endohedral fullerene-Al4C@C80.

Authors:  Qi Liang Lu; Wen Jun Song; Jun Wei Meng; Jian Guo Wan
Journal:  J Mol Model       Date:  2012-11-17       Impact factor: 1.810

Review 2.  The stabilization of fused-pentagon fullerene molecules.

Authors:  Yuan-Zhi Tan; Su-Yuan Xie; Rong-Bin Huang; Lan-Sun Zheng
Journal:  Nat Chem       Date:  2009-08-24       Impact factor: 24.427

3.  M2@C79N (M = Y, Tb): isolation and characterization of stable endohedral metallofullerenes exhibiting M-M bonding interactions inside aza[80]fullerene cages.

Authors:  Tianming Zuo; Liaosa Xu; Christine M Beavers; Marilyn M Olmstead; Wujun Fu; T Daniel Crawford; Alan L Balch; Harry C Dorn
Journal:  J Am Chem Soc       Date:  2008-09-06       Impact factor: 15.419

4.  Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.

Authors:  Katrin Junghans; Christin Schlesier; Aram Kostanyan; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Sandra Schiemenz; Rasmus Westerström; Thomas Greber; Bernd Büchner; Alexey A Popov
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-09       Impact factor: 15.336

5.  Transformation of doped graphite into cluster-encapsulated fullerene cages.

Authors:  Marc Mulet-Gas; Laura Abella; Maira R Cerón; Edison Castro; Alan G Marshall; Antonio Rodríguez-Fortea; Luis Echegoyen; Josep M Poblet; Paul W Dunk
Journal:  Nat Commun       Date:  2017-10-31       Impact factor: 14.919

6.  Qubit crossover in the endohedral fullerene Sc3C2@C80.

Authors:  Zheng Liu; Bo-Wei Dong; Hai-Bing Meng; Mei-Xing Xu; Tai-Shan Wang; Bing-Wu Wang; Chun-Ru Wang; Shang-Da Jiang; Song Gao
Journal:  Chem Sci       Date:  2017-11-02       Impact factor: 9.825

7.  Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene Dy2O@C82.

Authors:  Wei Yang; Georgios Velkos; Fupin Liu; Svetlana M Sudarkova; Yaofeng Wang; Jiaxin Zhuang; Hanning Zhang; Xiang Li; Xingxing Zhang; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov; Ning Chen
Journal:  Adv Sci (Weinh)       Date:  2019-08-15       Impact factor: 16.806

8.  An improbable monometallic cluster entrapped in a popular fullerene cage: YCN@C(s)(6)-C82.

Authors:  Shangfeng Yang; Chuanbao Chen; Fupin Liu; Yunpeng Xie; Fengyu Li; Mingzhi Jiao; Mitsuaki Suzuki; Tao Wei; Song Wang; Zhongfang Chen; Xing Lu; Takeshi Akasaka
Journal:  Sci Rep       Date:  2013       Impact factor: 4.379

9.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236

10.  Flexible decapyrrylcorannulene hosts.

Authors:  Yun-Yan Xu; Han-Rui Tian; Shu-Hui Li; Zuo-Chang Chen; Yang-Rong Yao; Shan-Shan Wang; Xin Zhang; Zheng-Zhong Zhu; Shun-Liu Deng; Qianyan Zhang; Shangfeng Yang; Su-Yuan Xie; Rong-Bin Huang; Lan-Sun Zheng
Journal:  Nat Commun       Date:  2019-01-30       Impact factor: 14.919
  10 in total

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