Literature DB >> 16136257

The synthesis of tris(perfluoroalkyl)phosphines.

Makeba B Murphy-Jolly1, Lesley C Lewis, Andrew J M Caffyn.   

Abstract

Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.

Entities:  

Year:  2005        PMID: 16136257     DOI: 10.1039/b507752d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis, Reactivity and Structural Properties of Trifluoromethylphosphoranides.

Authors:  Oleg O Shyshkov; Alexander A Kolomeitsev; Berthold Hoge; Enno Lork; Axel Haupt; Mira Keßler; Gerd-Volker Röschenthaler
Journal:  Chemistry       Date:  2022-02-09       Impact factor: 5.020

2.  Synthesis of 1-[bis(trifluoromethyl)phosphine]-1'-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates.

Authors:  Zeng-Wei Lai; Rong-Fei Yang; Ke-Yin Ye; Hongbin Sun; Shu-Li You
Journal:  Beilstein J Org Chem       Date:  2014-05-30       Impact factor: 2.883

  2 in total

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