Literature DB >> 16136246

A remarkably effective catalyst for the asymmetric transfer hydrogenation of aromatic ketones in water and air.

Xiaofeng Wu1, Daniele Vinci, Takao Ikariya, Jiangliang Xiao.   

Abstract

A Rh(III) complex generated in situ from [Cp*RhCl2]2 and (1R,2R)-N-(p-toluenesulfonyl)-1,2-cyclohexanediamine (TsCYDN) serves as a remarkably effective, robust catalyst for the asymmetric transfer hydrogenation of aromatic ketones by HCOONa in water in air, affording alcohols in up to 99% ee.

Entities:  

Year:  2005        PMID： 16136246     DOI： 10.1039/b507276j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Effect of dehydrogenation/hydrogenation on the linear and nonlinear optical properties of Li@porphyrins.

Authors:  Heng-Qing Wu; Shi-Ling Sun; Rong-Lin Zhong; Hong-Liang Xu; Zhong-Min Su
Journal:  J Mol Model       Date:  2012-06-22       Impact factor: 1.810

2.  pH-Dependent transfer hydrogenation or dihydrogen release catalyzed by a [(η6-arene)RuCl(κ2-N,N-dmobpy)]+ complex: a DFT mechanistic understanding.

Authors:  Chenguang Luo; Longfei Li; Xin Yue; Pengjie Li; Lin Zhang; Zuoyin Yang; Min Pu; Zexing Cao; Ming Lei
Journal:  RSC Adv       Date:  2020-03-11       Impact factor: 4.036
  2 in total

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