| Literature DB >> 16131173 |
Alan D Payne1, Anthony C Willis, Michael S Sherburn.
Abstract
Spectacular new atom efficient domino cycloaddition sequences involving [4]dendralene, the simplest cross-conjugated tetraene, are reported. Up to eight stereocenters, three new rings, and six C-C bonds are generated in one synthetic operation. The site selectivity of dienophile addition to cross-conjugated trienes and tetraenes is controlled with a simple Lewis acid.Entities:
Year: 2005 PMID: 16131173 DOI: 10.1021/ja053772+
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419