Literature DB >> 16131164

Copper complexes for fluorescence-based NO detection in aqueous solution.

Mi Hee Lim1, Stephen J Lippard.   

Abstract

Two copper(II) complexes containing dansylated ligands were investigated as turn-on fluorescence-based nitric oxide (NO) sensors. Upon addition of NO (g), the quenched fluorescence of both complexes was restored in both organic and buffered aqueous solutions, which is caused by the formation of a diamagnetic Cu(I) species and protonation of the sulfonamide functionality of the ligands. The NO detection limit of these Cu(II) complexes is 10 nM.

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Year:  2005        PMID: 16131164     DOI: 10.1021/ja053150o

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


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