Literature DB >> 16124019

Alkali-metal-mediated zincation of ferrocene: synthesis, structure, and reactivity of a lithium tmp/zincate reagent.

Helen R L Barley1, William Clegg, Sophie H Dale, Eva Hevia, Gordon W Honeyman, Alan R Kennedy, Robert E Mulvey.   

Abstract

Entities:  

Year:  2005        PMID： 16124019     DOI： 10.1002/anie.200501560

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


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  4 in total

1.  Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

Authors:  Ross Campbell; Daniel Cannon; Pablo García-Álvarez; Alan R Kennedy; Robert E Mulvey; Stuart D Robertson; Jörg Sassmannshausen; Tell Tuttle
Journal:  J Am Chem Soc       Date:  2011-08-04       Impact factor: 15.419

2.  A regioselectively 1,1',3,3'-tetrazincated ferrocene complex displaying core and peripheral reactivity.

Authors:  Gordon W Honeyman; David R Armstrong; William Clegg; Eva Hevia; Alan R Kennedy; Ross McLellan; Samantha A Orr; John A Parkinson; Donna L Ramsay; Stuart D Robertson; Stephen Towie; Robert E Mulvey
Journal:  Chem Sci       Date:  2020-03-27       Impact factor: 9.825

3.  Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates.

Authors:  William Clegg; Ben Conway; Eva Hevia; Matthew D McCall; Luca Russo; Robert E Mulvey
Journal:  J Am Chem Soc       Date:  2009-02-18       Impact factor: 15.419

4.  Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-TMP-zincate bases.

Authors:  William Clegg; Ben Conway; David V Graham; Eva Hevia; Alan R Kennedy; Robert E Mulvey; Luca Russo; Dominic S Wright
Journal:  Chemistry       Date:  2009-07-20       Impact factor: 5.236
  4 in total

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