| Literature DB >> 16119934 |
Masahiro Toyota1, Takeshi Asano, Masataka Ihara.
Abstract
Total syntheses of serofendic acids A (1a) and B (1b) are described. The key strategic element of the approach involves the novel tin-free homoallyl-homoallyl radical rearrangement of 5 for the construction of bicyclo[2.2.2]octane ring system 4. In addition, the conversion of methyl atisirenoate 2 to serofendic acids A (1a) and B (1b) was achieved on the basis of the Michael reaction of sodium thiomethoxide.[reaction: see text]Entities:
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Year: 2005 PMID： 16119934 DOI： 10.1021/ol051411t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005