Literature DB >> 16113722

High-nuclearity homometallic iron and nickel clusters: Fe22 and Ni24 complexes from the use of N-methyldiethanolamine.

Dolos Foguet-Albiol1, Khalil A Abboud, George Christou.   

Abstract

The use of N-methyldiethanolamine (mdaH2) in reactions with Fe(III) and Ni(II) sources has led to Fe22 and Ni24 products; the clusters are the highest and second-highest, respectively, homometallic clusters for these metals to date, and possess S = 0 and S = 6 ground states, respectively.

Entities:  

Year:  2005        PMID: 16113722     DOI: 10.1039/b507748f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Ultralarge 3d/4f Coordination Wheels: From Carboxylate/Amino Alcohol-Supported {Fe4Ln2} to {Fe18Ln6} Rings.

Authors:  Olga Botezat; Jan van Leusen; Victor Ch Kravtsov; Paul Kögerler; Svetlana G Baca
Journal:  Inorg Chem       Date:  2017-01-30       Impact factor: 5.165

  1 in total

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