Literature DB >> 16100613

Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution.

Yvonne Chiang1, A Jerry Kresge, Ikenna Onyido, John P Richard, Peter Wan, Musheng Xu.   

Abstract

Photodecarboxylation of p-benzoylphenylacetic acid in aqueous solution produces the elongated enol 5, whose strength as an oxygen acid (pQ(E/a)= 7.67) makes it more acidic than simple enol analogs by several orders of magnitude.

Entities:  

Year:  2005        PMID: 16100613     DOI: 10.1039/b506706e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  The Generation and Reactions of Quinone Methides.

Authors:  Maria M Toteva; John P Richard
Journal:  Adv Phys Org Chem       Date:  2011-01-01       Impact factor: 2.833

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.