| Literature DB >> 16092856 |
Chuang-Chuang Li1, Shuang Liang, Xin-Hao Zhang, Zhi-Xiang Xie, Jia-Hua Chen, Yun-Dong Wu, Zhen Yang.
Abstract
Construction of the [5-7-6] tricyclic core of guanacastepenes was attempted by using the intramolecular Diels-Alder (IMDA) reaction and Me(3)Al-mediated ring opening of the oxabridge as key synthetic steps. The illustrated chemistry demonstrated a synthetic feasibility to build up the framework of guanacastepenes by the IMDA reaction. [reaction: see text]Entities:
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Year: 2005 PMID： 16092856 DOI： 10.1021/ol051312f
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005