Literature DB >> 16092851

Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6.

Nan Jiang1, Arthur J Ragauskas.   

Abstract

A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO(4))(2)/DMAP in the ionic liquid [bmpy]PF(6) has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity. [reaction: see text]

Entities:  

Year:  2005        PMID： 16092851     DOI： 10.1021/ol051293+

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

Review 1.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

Review 2.  Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

Authors:  Bradford L Ryland; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

3.  Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation.

Authors:  Jessica M Hoover; Bradford L Ryland; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-01-31       Impact factor: 15.419

4.  Chemoselective Oxidation of Benzyl, Amino, and Propargyl Alcohols to Aldehydes and Ketones under Mild Reaction Conditions.

Authors:  C B Rajashekar Reddy; Sabbasani Rajasekhara Reddy; Shivaji Naidu
Journal:  ChemistryOpen       Date:  2014-12-10       Impact factor: 2.911
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.