Sub-Hertz optical frequency comparisons between two trapped 171Yb+ ions.

We compare the frequencies of the 6s2S(1/2)(F = 0)-->5d2D(3/2)(F = 2) reference transition in 171Yb+ for two single ions stored in independent traps. The quadrupole moment of the 5d2D(3/2) state is measured to be 9.32(48) x 10(-40) C m2 and from the quadratic Stark shift the relevant scalar and tensor polarizabilities are determined to be alphaS(S(1/2)) - alphaS(D(3/2)) = -6.9(1.4) x 10(-40) J m2/V2 and alphaT(D(3/2)) = -13.6(2.2) x 10(-40) J m2/V2, respectively. In the absence of external perturbations we find a mean frequency difference between the two trapped ions of 0.26(42) Hz, corresponding to a relative difference of 3.8(6.1) x 10(-16). This is comparable to the agreement found in the most accurate comparisons between cesium fountain clocks.