| Literature DB >> 16089419 |
M Paul Lettinga1, Zvonimir Dogic, Hao Wang, Jan Vermant.
Abstract
The behavior of a colloidal suspension of rodlike fd viruses in the nematic phase, subjected to steady state and transient shear flows, is studied. The monodisperse nature of these rods combined with relatively small textural contribution to the overall stress make this a suitable model system to investigate the effects of flow on the nonequilibrium phase diagram. Transient rheological experiments are used to determine the critical shear rates at which director tumbling, wagging, and flow-aligning occurs. The present model system enables us to study the effect of rod concentration on these transitions. The results are in quantitatively agreement with the Doi-Edwards-Hess model. Moreover, we observe that there is a strong connection between the dynamic transitions and structure formation, which is not incorporated in theory.Year: 2005 PMID: 16089419 DOI: 10.1021/la050116e
Source DB: PubMed Journal: Langmuir ISSN: 0743-7463 Impact factor: 3.882