Literature DB >> 16076184

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes.

Jing Zhang1, Gregory Leitus, Yehoshoa Ben-David, David Milstein.   

Abstract

An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H(2) under neutral conditions.

Entities:  

Year:  2005        PMID： 16076184     DOI： 10.1021/ja052862b

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  39 in total

1.  Ruthenium catalyzed C-C bond formation via transfer hydrogenation: branch-selective reductive coupling of allenes to paraformaldehyde and higher aldehydes.

Authors:  Ming-Yu Ngai; Eduardas Skucas; Michael J Krische
Journal:  Org Lett       Date:  2008-06-06       Impact factor: 6.005

2.  Bifunctional catalysis: a bridge from CO2 to methanol.

Authors:  Pierre H Dixneuf
Journal:  Nat Chem       Date:  2011-07-22       Impact factor: 24.427

3.  A sustainable catalytic pyrrole synthesis.

Authors:  Stefan Michlik; Rhett Kempe
Journal:  Nat Chem       Date:  2013-01-20       Impact factor: 24.427

4.  Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines.

Authors:  Nathan J Oldenhuis; Vy M Dong; Zhibin Guan
Journal:  Tetrahedron       Date:  2014-07-08       Impact factor: 2.457

5.  Nickel-catalyzed dehydrogenative cross-coupling: direct transformation of aldehydes into esters and amides.

Authors:  Aaron M Whittaker; Vy M Dong
Journal:  Angew Chem Int Ed Engl       Date:  2014-11-25       Impact factor: 15.336

6.  Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

Authors:  Ekambaram Balaraman; Chidambaram Gunanathan; Jing Zhang; Linda J W Shimon; David Milstein
Journal:  Nat Chem       Date:  2011-07-22       Impact factor: 24.427

7.  Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide.

Authors:  Martin Nielsen; Elisabetta Alberico; Wolfgang Baumann; Hans-Joachim Drexler; Henrik Junge; Serafino Gladiali; Matthias Beller
Journal:  Nature       Date:  2013-02-27       Impact factor: 49.962

8.  Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source.

Authors:  Ekambaram Balaraman; Eugene Khaskin; Gregory Leitus; David Milstein
Journal:  Nat Chem       Date:  2013-01-06       Impact factor: 24.427

9.  Proton-hydride tautomerism in hydrogen evolution catalysis.

Authors:  Luis M Aguirre Quintana; Samantha I Johnson; Sydney L Corona; Walther Villatoro; William A Goddard; Michael K Takase; David G VanderVelde; Jay R Winkler; Harry B Gray; James D Blakemore
Journal:  Proc Natl Acad Sci U S A       Date:  2016-05-24       Impact factor: 11.205

10.  A homogeneous transition metal complex for clean hydrogen production from methanol-water mixtures.

Authors:  Rafael E Rodríguez-Lugo; Mónica Trincado; Matthias Vogt; Friederike Tewes; Gustavo Santiso-Quinones; Hansjörg Grützmacher
Journal:  Nat Chem       Date:  2013-03-10       Impact factor: 24.427
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