Literature DB >> 16075075

Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates.

Tristram Chivers1, Dana J Eisler, Chantall Fedorchuk, Gabriele Schatte, Heikki M Tuononen, René T Boeré.   

Abstract

Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(mu-NtBu)2]2M} are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems.

Entities:  

Year:  2005        PMID： 16075075     DOI： 10.1039/b506253e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Combined QTAIM and ETS-NOCV investigation of the interactions in ClnM[PhB(NtBu)2] complexes with M = Si & Ge (n = 0), As & Sb (n = 1), Te & Po (n = 2).

Authors:  Salima Lakehal; Aicha Lakehal; Malika Bouchagour; Christophe Morell; Henry Chermette
Journal:  J Mol Model       Date:  2018-10-29       Impact factor: 1.810

2.  Aluminium alkyl complexes supported by imino-phosphanamide ligand as precursors for catalytic guanylation reactions of carbodiimides.

Authors:  Himadri Karmakar; Srinivas Anga; Tarun K Panda; Vadapalli Chandrasekhar
Journal:  RSC Adv       Date:  2022-02-03       Impact factor: 3.361
  2 in total

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