Literature DB >> 16045326

Modular monodentate phosphoramidite ligands for rhodium-catalyzed enantioselective hydrogenation.

Yan Liu1, Kuiling Ding.   

Abstract

A new class of monodentate phosphoramidite ligands (DpenPhos) has been developed on the basis of the modular concept for Rh(I)-catalyzed asymmetric hydrogenations of a variety of olefin derivatives, affording the corresponding optically active compounds in excellent yields and enantioselectivities. The ligands have the advantages of facile preparation, tunable structure, and broad scope of substrates in their Rh(I) complex-catalyzed asymmetric hydrogenations.

Entities:  

Year:  2005        PMID： 16045326     DOI： 10.1021/ja052749l

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

Authors:  Craig R Smith; Daniel J Mans; T V Rajanbabu; Scott E Denmark; Son T Nguyen
Journal:  Organic Synth       Date:  2008

2.  Efficient synthesis of chiral beta-arylisopropylamines by using catalytic asymmetric hydrogenation.

Authors:  Jian Chen; Weicheng Zhang; Huiling Geng; Wei Li; Guohua Hou; Aiwen Lei; Xumu Zhang
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

3.  2,2'-[(1S,2S)-1,2-Bis(2-hy-droxy-phen-yl)ethane-1,2-di-yl]bis(isoindoline-1,3-dione) ethanol monosolvate hemihydrate.

Authors:  Jik Chin; Dongsoo Koh; Alan J Lough
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-02-20
  3 in total

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