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Literature DB >> 16041425

A new synthetic route to bulky "second generation" tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(II) complex.

Ismael Nieto¹, Francisco Cervantes-Lee, Jeremy M Smith.

Abstract

A bulky tripodal tris(carbene)borate ligand, prepared from 1-tert-butylimidazole, is cleanly transferred to iron(II) by a magnesium reagent.

Entities: Chemical

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Year: 2005 PMID： 16041425 DOI： 10.1039/b505985b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.

Authors: Gaël Ung; Jonas C Peters
Journal: Angew Chem Int Ed Engl Date: 2014-11-13 Impact factor: 15.336

2. M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

Authors: Caroline T Saouma; Jonas C Peters
Journal: Coord Chem Rev Date: 2011-04 Impact factor: 22.315

3. Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes.

Authors: Salvador B Muñoz; Wallace K Foster; Hsiu-Jung Lin; Charles G Margarit; Diane A Dickie; Jeremy M Smith
Journal: Inorg Chem Date: 2012-11-09 Impact factor: 5.165

A new synthetic route to bulky "second generation" tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(II) complex.

1. Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.

2. M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

3. Tris(carbene)borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1,3,4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO}10 complexes.

4. Coordination chemistry of poly(thioether)borate ligands.

5. Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8).

6. A Low Spin Manganese(IV) Nitride Single Molecule Magnet.