Literature DB >> 16028938

Gamma-Fe2O3/II-VI sulfide nanocrystal heterojunctions.

Kwan-Wook Kwon1, Moonsub Shim.   

Abstract

Heterostructure nanocrystals (NCs) of gamma-Fe(2)O(3) and MS (M = Zn, Cd, Hg) are synthesized. The large lattice mismatch between gamma-Fe(2)O(3) and MS NCs leads to noncentrosymmetric structures. Crystallographic planes at the heterojunctions are identified by high-resolution transmission electron microscopy. Preferential formation of trimers and higher oligomers for ZnS and dimers or isolated particles for CdS and HgS with gamma-Fe(2)O(3) NCs are observed and explained by changes in the effective mismatch between the coincidence lattices of the most commonly observed junction planes.

Entities:  

Year:  2005        PMID: 16028938     DOI: 10.1021/ja051713q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  14 in total

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