| Literature DB >> 16028938 |
Kwan-Wook Kwon1, Moonsub Shim.
Abstract
Heterostructure nanocrystals (NCs) of gamma-Fe(2)O(3) and MS (M = Zn, Cd, Hg) are synthesized. The large lattice mismatch between gamma-Fe(2)O(3) and MS NCs leads to noncentrosymmetric structures. Crystallographic planes at the heterojunctions are identified by high-resolution transmission electron microscopy. Preferential formation of trimers and higher oligomers for ZnS and dimers or isolated particles for CdS and HgS with gamma-Fe(2)O(3) NCs are observed and explained by changes in the effective mismatch between the coincidence lattices of the most commonly observed junction planes.Entities:
Year: 2005 PMID: 16028938 DOI: 10.1021/ja051713q
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419