Literature DB >> 16028926

Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant.

John D Gilbertson1, Nathaniel K Szymczak, David R Tyler.   

Abstract

The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of both H2 and N2 to produce ammonia and hydrazine. A Leigh-type cycle was employed to achieve laboratory fixation of dinitrogen at room temperature and pressure utilizing H2 as the reductant.

Entities:  

Year:  2005        PMID： 16028926     DOI： 10.1021/ja053030g

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

1.  Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.

Authors:  Gaël Ung; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2014-11-13       Impact factor: 15.336

2.  N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex.

Authors:  Meghan M Rodriguez; Eckhard Bill; William W Brennessel; Patrick L Holland
Journal:  Science       Date:  2011-11-11       Impact factor: 47.728

Review 3.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

4.  N2 functionalization at iron metallaboratranes.

Authors:  Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-10-21       Impact factor: 15.419

5.  Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.

Authors:  Sidney E Creutz; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2014-01-09       Impact factor: 15.419

6.  Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

Authors:  Kristian E Dalle; Julien Warnan; Jane J Leung; Bertrand Reuillard; Isabell S Karmel; Erwin Reisner
Journal:  Chem Rev       Date:  2019-02-15       Impact factor: 60.622

7.  (Ethane-1,2-di-yl)bis-[bis-(3-methoxy-prop-yl)methyl-phospho-nium] bis-(tetra-phenyl-borate) diethyl ether solvate.

Authors:  Justin L Crossland; Lev N Zakharov; David R Tyler
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-05-17

8.  Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen.

Authors:  Keying Ding; William W Brennessel; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2009-08-12       Impact factor: 15.419

9.  Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges.

Authors:  Thomas R Dugan; K Cory Macleod; William W Brennessel; Patrick L Holland
Journal:  Eur J Inorg Chem       Date:  2013-08-01       Impact factor: 2.524

10.  Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.

Authors:  Yang Li; Ying Li; Baomin Wang; Yi Luo; Dawei Yang; Peng Tong; Jinfeng Zhao; Lun Luo; Yuhan Zhou; Si Chen; Fang Cheng; Jingping Qu
Journal:  Nat Chem       Date:  2013-03-17       Impact factor: 24.427
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