Literature DB >> 16018717

A straightforward synthesis of ynones by reaction of dimethylalkynylaluminum reagents with acid chlorides.

Baomin Wang1, Martine Bonin, Laurent Micouin.   

Abstract

Alkynyldimethylaluminum reagents react with various aromatic and aliphatic acid chlorides in a fast and efficient way. This reaction provides a simple entry to numerous ynones, using readily available, inexpensive, and nontoxic metalating agent, and does not require any transition metal as a catalyst.

Entities:  

Year:  2005        PMID： 16018717     DOI： 10.1021/jo050760y

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Calixarene alpha-ketoacetylenes: versatile platforms for reaction with hydrazine nucleophile.

Authors:  Anton A Muravev; Svetlana E Solovieva; Farida B Galieva; Olga B Bazanova; Ildar Kh Rizvanov; Kamil A Ivshin; Olga N Kataeva; Susan E Matthews; Igor S Antipin
Journal:  RSC Adv       Date:  2018-09-21       Impact factor: 3.361

2.  5-Hydroxyindoles by intramolecular alkynol-furan diels-alder cycloaddition.

Authors:  Matthew LaPorte; Ki Bum Hong; Jie Xu; Peter Wipf
Journal:  J Org Chem       Date:  2012-11-16       Impact factor: 4.354
  2 in total

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